Synthesis and catalysis of tungsten oxide in hexagonal mesoporous silicas (W-HMS)

• Published in: Applied catalysis. A, General Vol. 317; no. 1; pp. 91 - 96
• Main Authors: Ke, Iou-Sheng, Liu, Shiuh-Tzung
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 27.01.2007; Elsevier
• Subjects: Catalysis; Chemistry; Colloidal state and disperse state; Cyclohexene; Exact sciences and technology; General and physical chemistry; Oxidation; Porous materials; Silicas; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Tungsten; Oxidation; Cyclohexene; Tungsten; Silicas; Heterogeneous catalysis; Tungsten oxide; Catalytic reaction; Synthesis; Porous material; Silica; Ethylenic compound; Mesoporosity
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2006.10.007

By using a diblock copolymer containing tungsten complexes as templates, tungsten-hexagonal mesoporous silicas (W-HMS) were synthesized, which could be used as a catalyst for the allylic oxidation of cyclohexene. ▪ Hexagonal mesoporous silicas containing tungsten complexes have been synthesized through the condensation of tetraethoxysilane templated by an amphiphilic diblock copolymers modified with tungsten isocyanide complexes under acidic conditions. Upon calcination, the tungsten complex was transformed into its oxide, which was deposited inside the channels. This material is illustrated to be a good catalyst on the allylic oxidation of cyclohexene in the presence of hydrogen peroxide under mild conditions. In addition, this catalyst could be easily recovered after the reaction and re-used without any significant loss of its activity.