Evaluation of the use of degummed soybean oil and supercritical ethanol for non-catalytic biodiesel production
[Display omitted] •The production of biodiesel from degummed soy bean oil and supercritical ethanol was investigated.•The effects of residence time, temperature and ethanol:oil molar ratio were evaluated using design of experiments.•It was possible to obtain yields of fatty acid ethyl esters up to 6...
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Published in | The Journal of supercritical fluids Vol. 105; pp. 21 - 28 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.10.2015
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Subjects | |
Online Access | Get full text |
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Summary: | [Display omitted]
•The production of biodiesel from degummed soy bean oil and supercritical ethanol was investigated.•The effects of residence time, temperature and ethanol:oil molar ratio were evaluated using design of experiments.•It was possible to obtain yields of fatty acid ethyl esters up to 65% in the experimental range studied.
In this work the production of fatty acid ethyl esters (FAEE) from degummed soybean oil in supercritical ethanol was investigated. The process parameters were defined as reaction temperature (250–340°C), residence time (11–50min) and ethanol:oil molar ratio (9:1–51:1). All experiments were performed in a continuous reactor at 20MPa. The effect of each parameter and their interactions on the yield of fatty acid ethylic esters was studied using design of experiments (DOE). Results showed that all three single parameters were significant on the yield of FAEE and that reactions of degummed soybean oil with ethanol led to esters yields up to 65%, in these experimental conditions. These values are inferior when compared to the ones obtained with refined soybean oil probably due to the presence of several impurities in degummed soy bean oil such as pigments, antioxidants and phospholipids. Despite of this lower yield, the use of degummed soybean oil can still be a good alternative since this is a non-edible lower cost raw material. |
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ISSN: | 0896-8446 1872-8162 |
DOI: | 10.1016/j.supflu.2015.05.017 |