Revealing Mode Formation in Quasi‐Bound States in the Continuum Metasurfaces via Near‐Field Optical Microscopy

• Published in: Advanced materials (Weinheim) Vol. 36; no. 38; pp. e2405978 - n/a
• Main Authors: Gölz, Thorsten, Baù, Enrico, Aigner, Andreas, Mancini, Andrea, Barkey, Martin, Keilmann, Fritz, Maier, Stefan A., Tittl, Andreas
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.09.2024
• Subjects: bound states in the continuum; Defects; Edge effect; Image enhancement; Image processing; Metasurfaces; Microscopy; mid‐infrared; near‐field microscopy; Nonlinear control; Nonlinear optics; optical metasurfaces; Optical microscopy; Resonators; Size effects; SNOM; bound states in the continuum; optical metasurfaces; mid‐infrared; near‐field microscopy; SNOM
• ISSN: 0935-9648; 1521-4095; 1521-4095
• DOI: 10.1002/adma.202405978

Photonic metasurfaces offer exceptional control over light at the nanoscale, facilitating applications spanning from biosensing, and nonlinear optics to photocatalysis. Many metasurfaces, especially resonant ones, rely on periodicity for the collective mode to form, which makes them subject to the influences of finite size effects, defects, and edge effects, which have considerable negative impact at the application level. These aspects are especially important for quasi‐bound state in the continuum (BIC) metasurfaces, for which the collective mode is highly sensitive to perturbations due to high‐quality factors and strong near‐field enhancement. Here, the mode formation in quasi‐BIC metasurfaces on the individual resonator level using scattering scanning near‐field optical microscopy (s‐SNOM) in combination with a new image processing technique, is quantitatively investigated. It is found that the quasi‐BIC mode is formed at a minimum size of 10 × 10‐unit cells much smaller than expected from far‐field measurements. Furthermore, it is shown that the coupling direction of the resonators, defects and edge states have pronounced influence on the quasi‐BIC mode. This study serves as a link between the far‐field and near‐field responses of metasurfaces, offering crucial insights for optimizing spatial footprint and active area, holding promise for augmenting applications such as catalysis and biospectroscopy. A near‐field microscopy technique is introduced that resolves and quantifies quasi‐bound state in the continuum modes in dielectric metasurfaces. The technique is employed for analyzing metasurface properties such as the finite array size effect, directional coupling, edge effects and defects on the single resonator level promising advancements in metasurface based catalysis and biospectroscopy by optimizing spatial footprint and active area.