Single parameter synthesis of high silica CHA zeolites from fluoride media

• Published in: Microporous and mesoporous materials Vol. 153; pp. 94 - 99
• Main Authors: Eilertsen, Einar A., Arstad, Bjørnar, Svelle, Stian, Lillerud, Karl P.
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 01.05.2012; Elsevier
• Subjects: CHA; Chabazite; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; High silica; Ion-exchange; Porous materials; Si/Al; SSZ-13; Surface physical chemistry; Zeolites: preparations and properties; SSZ-13; Chabazite; High silica; CHA; Si/Al; Scanning electron microscopy; Binary compound; Particle size; Hydroxides; NMR spectrometry; Crystallinity; Fluorides; Zeolite; X ray diffraction; Porous material; Silica; Molecular sieve; Powder; Template; Synthesis; Silicon oxides; Surface area
• ISSN: 1387-1811; 1873-3093
• DOI: 10.1016/j.micromeso.2011.12.026

[Display omitted] ► Synthesis of CHA zeolites with single parameter variation. ► CHA zeolites have been synthesized covering Si/Al ratios from 20 to SiO2. ► The particle size and the surface area are not affected by the change in Si/Al. A series of high silica CHA zeolites with a true single parameter variation has been synthesized, where only the Si/Al ratio changes, using N,N,N-1-trimethyladamantammonium hydroxide as the structure directing agent in fluoride media. The materials have been synthesized with high crystallinity, and with a Si/Al ratio ranging from 20 to infinity, i.e. pure SiO2. Powder XRD shows that the unit cell parameters increase with increasing amount of Al incorporated into the framework, while BET and SEM shows that the specific surface area and the particle size is fairly independent of the Si/Al ratio. We also present an explanation for the earlier reported disagreement in Si/Al ratio determined by elemental analysis and 29Si MAS NMR.