Molecular structures of n-type semiconducting material 2,5-difluoro-1,4-phenylene-3,3′-bis{2-[(4-trifluoromethyl)phenyl]acrylonitrile} and its photo dimerization product

The absolute molecular structure of air stable n-type semiconducting material 2,5-difluoro-1,4-phenylene-3,3′-bis{2-[(4-trifluoromethyl)phenyl]acrylonitrile} was determined by using twin crystal treatment X-ray diffraction analysis. The compound was readily dimerized in solution via irradiating of U...

Full description

Saved in:
Bibliographic Details
Published inJournal of molecular structure Vol. 1118; pp. 372 - 377
Main Authors Moriguchi, Tetsuji, Kitou, Naoya, Jalli, Venkataprasad, Yoza, Kenji, Nagamatsu, Shuichi, Okauchi, Tatsuo, Tsuge, Akihiko, Takashima, Wataru
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.08.2016
Subjects
Crystal structure
Diffraction
Dimerization
Dimers
Molecular packing
Molecular structure
N-type semiconductors
Organic semiconducting material
Photo dimerization
Sun
X-ray analysis
X-rays
π-Conjugated structure
Organic semiconducting material
Molecular packing
Photo dimerization
X-ray analysis
π-Conjugated structure
Online AccessGet full text

Cover

More Information
Summary:The absolute molecular structure of air stable n-type semiconducting material 2,5-difluoro-1,4-phenylene-3,3′-bis{2-[(4-trifluoromethyl)phenyl]acrylonitrile} was determined by using twin crystal treatment X-ray diffraction analysis. The compound was readily dimerized in solution via irradiating of UV or Sun light. The exact molecular structure of the dimer also determined by X-ray analysis. [Display omitted]
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2016.04.035