Design and performance of chromium mist generator

• Published in: Journal of the Brazilian Chemical Society Vol. 17; no. 2; pp. 342 - 347
• Main Authors: Tirgar, Aram, Golbabaei, Farideh, Nourijelyani, Keramat, Shahtaheri, Seyed Jamaleddin, Ganjali, Mohammad Reza, Hamedi, Javad
• Format: Journal Article
• Language: English
• Published: Sociedade Brasileira de Química 01.04.2006
• Subjects: CHEMISTRY, MULTIDISCIPLINARY; hexavalent chromium; mist generator; samplers distance; sampling height; side-by-side sampling; samplers distance; mist generator; hexavalent chromium; sampling height; side-by-side sampling
• ISSN: 0103-5053; 1678-4790; 1678-4790
• DOI: 10.1590/S0103-50532006000200018

Chromium mist generator is an essential tool for conducting researches and making science-based recommendations to evaluate air pollution and its control systems. The purpose of this research was to design and construct a homogenous chromium mist generator and the study of some effective factors including sampling height and distances between samplers in side-by-side sampling on chromium mist sampling method. A mist generator was constructed, using a chromium electroplating bath in pilot scale. Concentration of CrO3 and sulfuric acid in plating solution was 125 g L-1 and 1.25 g L-1, respectively. In order to create permanent air sampling locations, a Plexiglas cylindrical chamber (75 cm height, 55 cm i.d) was installed the bath overhead. Sixty holes were produced on the chamber in 3 rows (each 20). The distance between rows and holes was 15 and 7.5 cm, respectively. Homogeneity and effective factors were studied via side-by-side air sampling method. So, 48 clusters of samples were collected on polyvinyl chloride (PVC) filters housed in sampling cassettes. Cassettes were located in 35, 50, and 65 cm above the solution surface with less than 7.5 and/or 7.5-15 cm distance between heads. All samples were analyzed according to the NIOSH method 7600. According to the ANOVA test, no significant differences were observed between different sampling locations in side-by-side sampling (P=0.82) and between sampling heights and different samplers distances (P=0.86 and 0.86, respectively). However, there were notable differences between means of coefficient of variations (CV) in various heights and distances. It is concluded that the most chromium mist homogeneity could be obtained at height 50 cm from the bath solution surface and samplers distance of < 7.5 cm.