Preparation and Properties of Epoxy Modified Acrylic Polymer

• Published in: Polymers Vol. 17; no. 3; p. 380
• Main Authors: Zhou, Shiyan, Ma, Jinmei, Yu, Jun-Wen, Gao, Zhigang, Li, Fei, Zhang, Fenghua, He, Yu-Peng
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 30.01.2025; MDPI
• Subjects: Acrylic acid; Acrylic resins; Addition polymerization; Analysis; Aqueous solutions; Chemical synthesis; Cost effectiveness; Emulsion polymerization; Epoxy resins; Fourier transforms; Free radicals; Hydrogen bonds; Infrared analysis; Infrared spectroscopy; Molecular chains; Monomers; Particle size; Polymerization; Polymers; Reaction mechanisms; Reducing agents; Surfactants; Temperature; Thermal degradation; Thermal stability; Viscosity; Water; Weight loss; Zeta potential; China; Beijing China; Shanghai China; epoxy acrylate viscosity reducer; heavy oil reduces viscosity; viscosity reduction
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym17030380

This paper describes the synthesis of a viscosity-reducing agent using butyl acrylate (BA), ethyl methacrylate (EMA), acrylic acid (AA) and N-hydroxymethylacrylamide (N-MAM) monomers through emulsion polymerization. A series of viscosity-reducing agents were developed by incorporating varying amounts of glycidyl methacrylate (GMA) monomers. The reaction mechanism of epoxy acrylate viscosity reducer was analyzed by Fourier transform infrared spectroscopy (FTIR). Additionally, the particle size and Zeta potential were used to analyze the stability of the polymer and the difference in the polymer after adding GMA monomer. Thermogravimetric (TG) analysis indicated a significant improvement in the thermal stability of the resin due to GMA modification. The viscosity reduction test results demonstrated a substantial decrease in the viscosity of heavy oil, along with a notable increase in the viscosity reduction rate. The FTIR analysis results confirmed that GMA successfully introduced polyacrylate molecular chains. Furthermore, particle size and Zeta potential measurements showed that the average particle size of the emulsion increased from 132 nm to 187 nm, while the Zeta potential changed from −43 mV to −40 mV with the addition of 15% GMA. Compared with W0, the final thermal degradation temperature of W15 increased from 450 °C to 517 °C. When the GMA content reached 15 wt%, the maximum weight loss temperature increased by approximately 12 °C compared to the sample without GMA. Specifically, adding 8% W15 epoxy acrylate resulted in an 89% viscosity reduction rate for heavy oil, demonstrating an excellent viscosity reduction effect. This study successfully developed a novel epoxy acrylate viscosity reducer using a simple synthesis method, showcasing excellent stability, cost-effectiveness and remarkable viscosity reduction.