Development and Characterization of Polylactide Blends with Improved Toughness by Reactive Extrusion with Lactic Acid Oligomers

• Published in: Polymers Vol. 14; no. 9; p. 1874
• Main Authors: Tejada-Oliveros, Ramon, Fiori, Stefano, Gomez-Caturla, Jaume, Lascano, Diego, Montanes, Nestor, Quiles-Carrillo, Luis, Garcia-Sanoguera, David
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 04.05.2022; MDPI
• Subjects: Biodegradation; Brittleness; Dicumyl peroxide; environmentally friendly; Evaluation; Extrusion molding; Extrusion rate; Feasibility studies; Food packaging; Free radicals; Impact resistance; Impact strength; improved toughness; Injection molding; Lactic acid; lactic acid oligomer (OLA); maleinized linseed oil (MLO); Mixtures; Morphology; Oligomers; Polylactic acid; polylactide (PLA); Polymer blends; reactive extrusion; Toughness; Vegetable oils; Viscosity; Wetting; Spain; lactic acid oligomer (OLA); polylactide (PLA); improved toughness; environmentally friendly; reactive extrusion; maleinized linseed oil (MLO)
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym14091874

In this work, we report the development and characterization of polylactide (PLA) blends with improved toughness by the addition of 10 wt.% lactic acid oligomers (OLA) and assess the feasibility of reactive extrusion (REX) and injection moulding to obtain high impact resistant injection moulded parts. To improve PLA/OLA interactions, two approaches are carried out. On the one hand, reactive extrusion of PLA/OLA with different dicumyl peroxide (DCP) concentrations is evaluated and, on the other hand, the effect of maleinized linseed oil (MLO) is studied. The effect of DCP and MLO content used in the reactive extrusion process is evaluated in terms of mechanical, thermal, dynamic mechanical, wetting and colour properties, as well as the morphology of the obtained materials. The impact strength of neat PLA (39.3 kJ/m ) was slightly improved up to 42.4 kJ/m with 10 wt.% OLA. Nevertheless, reactive extrusion with 0.3 phr DCP (parts by weight of DCP per 100 parts by weight of PLA-OLA base blend 90:10) led to a noticeable higher impact strength of 51.7 kJ/m , while the reactive extrusion with 6 phr MLO gave an even higher impact strength of 59.5 kJ/m , thus giving evidence of the feasibility of these two approaches to overcome the intrinsic brittleness of PLA. Therefore, despite MLO being able to provide the highest impact strength, reactive extrusion with DCP led to high transparency, which could be an interesting feature in food packaging, for example. In any case, these two approaches represent environmentally friendly strategies to improve PLA toughness.