Structural characterization and catalytic activity of molybdenum oxide supported zirconia catalysts

• Published in: Microporous and mesoporous materials Vol. 102; no. 1; pp. 128 - 137
• Main Authors: El-Sharkawy, E.A., Khder, A.S., Ahmed, A.I.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 04.05.2007; Elsevier
• Subjects: Catalysis; Chemistry; Colloidal state and disperse state; Cumene cracking; Ethanol dehydration; Exact sciences and technology; General and physical chemistry; Molybdenum oxide; Porous materials; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Zirconia; Zirconia; Molybdenum oxide; Ethanol dehydration; Cumene cracking; Catalytic reaction; Hydrocarbon; Ethanol; Transition element compounds; Alcohol; Dehydration; Supported catalyst; Characterization; Heterogeneous catalysis; Alkanol; Benzenic compound; Cumene; Catalyst support
• ISSN: 1387-1811; 1873-3093
• DOI: 10.1016/j.micromeso.2006.12.037

A series of MoO 3/ZrO 2 catalysts with different molybdenum content of 5–30 wt.% MoO 3 were prepared by impregnation method. The prepared catalysts were calcined at 400, 550, 700, 800, and 1000 °C. The structural characteristics were investigated by means of thermal analysis (DTA and TGA), powder X-ray diffraction (XRD) while the textural properties was determined from low temperatures adsorption of N 2 at −196 °C. The surface acidity was measured with nonaqueous titration of n-butylamine in acetonitrile. The catalytic activity was tested by cumene dealkylation and ethanol conversion using the microcatalytic pulse technique. XRD reveals that the samples contain mixture of tetragonal and monoclinic zirconia phases. At low MoO 3 loading, i.e. <15 wt.% MoO 3, MoO 3 was not detected. When the loading of MoO 3 exceeds 15 wt.%, crystalline MoO 3 and Zr(MoO 4) 2 were formed, particularly for the higher calcination temperature products. The incorporation of MoO 3 into ZrO 2 enhanced the surface acidity of the catalysts. It was found that the surface acidity gradually increased as the temperature of thermal treatment was increased from 400 to 550 °C and also with the molybdenum oxide content. This increase in the surface acidity was correlated with the degrees of crystallinity of the samples. The surface area was found to increase with increasing of MoO 3 up to 15 wt.%. Further increase of MoO 3 beyond 15 wt.% led to a decrease of N 2- S BET. The catalytic activity was strongly influenced with the textural, structural properties and surface acidities of the catalysts investigated.