Fast Synthesis of PbS Nanocrystals in Aqueous Solution with Shape Evolution from Cubic to Octahedral Structures and Their Assembled Structures

• Published in: Chemistry : a European journal Vol. 18; no. 45; pp. 14473 - 14478
• Main Authors: Wu, Jian-Kuan, Lyu, Lian-Ming, Liao, Ching-Wen, Wang, Yu-Ning, Huang, Michael H.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 05.11.2012; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: assembly patterns; Chemistry; lead sulfide; nanostructures; self-assembly; shape evolution
• ISSN: 0947-6539; 1521-3765
• DOI: 10.1002/chem.201201687

In this study, we have developed for the first time a fast and energy‐efficient method for the synthesis of PbS nanocrystals with systematic shape evolution from cubic to truncated cubic, cuboctahedral, truncated octahedral, and octahedral structures. The method involves the addition of a small volume of preheated lead acetate and thioacetamide (TAA) mixture to an aqueous growth solution of lead acetate, thioacetamide, cetyltrimethylammonium bromide, and nitric acid. By varying the amount of thioacetamide added to the growth solution, PbS nanocrystals with different morphologies were generated in 2 h at 90 °C. Slight experimental modifications were adopted to generate truncated octahedra. The nanocrystals have very uniform dimensions with average sizes of 32–47 nm. Their structures have been extensively examined by electron microscopy. Nanocube sizes can also be tuned within a range. UV/Vis absorption spectra of PbS cubes, cuboctahedra, and octahedra all show decreasing but continuous absorption from 300 nm to beyond 1000 nm. By monitoring the speed of darkening of solution color, particle growth rate was found to be fastest for nanocubes, followed by truncated cubes, cuboctahedra, and octahedra. These monodisperse nanocrystals can readily form self‐assembled structures. Truncated cubes and octahedra that form monolayer and multilayer packing arrangements have also been studied. This green approach to the synthesis of PbS nanocrystals with fine size and shape control should allow for investigations of their facet‐dependent properties and the fabrication of novel heterostructures. Shape shifters: A fast and energy‐efficient method for the synthesis of PbS nanocrystals with systematic shape evolution from cubic to truncated cubic, cuboctahedral, truncated octahedral, and octahedral structures has been developed (see figure). By varying the amount of thioacetamide added to the growth solution, PbS nanocrystals with different morphologies were generated in 2 h at 90 °C.