Preparation of Highly Luminescent CdTe/CdS Core/Shell Quantum Dots

• Published in: Chemphyschem Vol. 10; no. 4; pp. 680 - 685
• Main Authors: Wang, Jian, Long, Yitao, Zhang, Yuliang, Zhong, Xinhua, Zhu, Linyong
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 09.03.2009; WILEY‐VCH Verlag; Wiley
• Subjects: Cadmium - chemistry; Chemistry; Colloidal state and disperse state; core/shell structures; Exact sciences and technology; General and physical chemistry; Luminescence; Metal Nanoparticles - chemistry; Microscopy, Electron, Transmission; nanoparticles; Nanostructures - chemistry; Nanostructures - ultrastructure; Oils - chemistry; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Quantum Dots; surfactants; Tellurium - chemistry; X-Ray Diffraction; Binary compound; Quantum dot; Nanoparticle; Transition element compounds; Luminescence; nanoparticles; quantum dots; surfactants; Surfactant; Quantum yield; Cadmium sulfide; core/shell structures; Preparation; Cadmium tellurides; Structure
• ISSN: 1439-4235; 1439-7641
• DOI: 10.1002/cphc.200800672

A good balance: Oil‐soluble CdTe/CdS core/shell quantum dots (QDs) that emit in the visible and near‐infrared spectral regions with quantum yields up to 92 % (see figure) are prepared by balancing the coordinating capacity and the activation effect of selected surfactants. An effective shell‐coating route is developed for covering oil‐soluble CdTe quantum dots (QDs), which usually tend to aggregate during the heating‐up process involved in shell formation. The new route is based on balancing the coordinating capacity and the activation effect of selected surfactants. The thus obtained highly luminescent CdTe/CdS core/shell QDs exhibit photoluminescence quantum yields as high as 92 %—among the best results obtained so far for luminescent semiconductor nanocrystals. By changing the size of the CdTe core, or the thickness of the CdS shell, the emission colors of the obtained core/shell nanocrystals can be tuned between the visible and near‐infrared regions of the spectrum following an identical procedure. A good balance: Oil‐soluble CdTe/CdS core/shell quantum dots (QDs) that emit in the visible and near‐infrared spectral regions with quantum yields up to 92 % (see figure) are prepared by balancing the coordinating capacity and the activation effect of selected surfactants.