Catalytic hydroxylation using chloroplatinum compounds

Using “PtCl 4” as the Pt(IV) component in the mixture of aqueous chloroPt(II)/chloroPt(IV) compounds makes the “Shilov” functionalization of alkyl groups considerably faster and more chemoselective to alcohols, and adding hydrogen peroxide re-oxidizes the Pt(II) reduction product to Pt(IV). Run in t...

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Bibliographic Details
Published inJournal of molecular catalysis. A, Chemical Vol. 189; no. 1; pp. 17 - 22
Main Authors DeVries, N., Roe, D.C., Thorn, D.L.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 16.10.2002
Subjects
Catalytic hydroxylation
Chloroplatinum compounds
Shilov
Chloroplatinum compounds
Catalytic hydroxylation
Shilov
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Summary:Using “PtCl 4” as the Pt(IV) component in the mixture of aqueous chloroPt(II)/chloroPt(IV) compounds makes the “Shilov” functionalization of alkyl groups considerably faster and more chemoselective to alcohols, and adding hydrogen peroxide re-oxidizes the Pt(II) reduction product to Pt(IV). Run in this manner, the reaction system is long-lived and catalytic in platinum. Using “PtCl 4” as the Pt(IV) component in the mixture of aqueous chloroPt(II)/chloroPt(IV) compounds makes the “Shilov” functionalization of alkyl groups considerably faster and more chemoselective to alcohols, and adding hydrogen peroxide re-oxidizes the Pt(II) reduction product to Pt(IV). Run in this manner, the reaction system is long-lived and catalytic in platinum.
ISSN:1381-1169
1873-314X
DOI:10.1016/S1381-1169(02)00194-2