Development of a new solvent extraction process based on butyl-1-[N,N-bis(2-ethylhexyl)carbamoyl]nonyl phosphonic acid for the selective recovery of uranium(VI) from phosphoric acid

• Published in: Solvent extraction and ion exchange Vol. 34; no. 3; pp. 274 - 289
• Main Authors: Miguirditchian, M., Bernier, G., Pacary, V., Balaguer, C., Sorel, C., Berlemont, R., Fries, B., Bertrand, M., Camès, B., Leydier, A., Turgis, R., Arrachart, G., Pellet-Rostaing, S., Mokhtari, H.
• Format: Journal Article
• Language: English
• Published: Taylor & Francis 15.04.2016
• Subjects: Chemical Sciences; DEHCNPB; iron(III); phosphoric acid; process modeling; solvent extraction; uranium(VI)
• ISSN: 0736-6299; 1532-2262
• DOI: 10.1080/07366299.2016.1169147

The promising new extractant molecule butyl-1-[N,N-bis(2-ethylhexyl)carbamoyl]nonyl phosphonic acid (DEHCNPB) was designed and used to develop a new solvent extraction process for the selective recovery of uranium from phosphoric acid. This bifunctional extracting molecule shows high affinity and selectivity for uranium(VI) versus iron(III) and the other elements present in phosphoric acid (Al, Ti, V, etc.). Batch equilibrium experiments were first carried out to determine the stoichiometries of the different complexes formed with uranium(VI) and iron(III) in organic phase and to optimize the different steps of the process at laboratory scale. These experimental data were then used to develop a chemical model to simulate uranium(VI) and iron(III) extraction from phosphoric acid, which was implemented in the PAREX simulation code. A flowsheet was calculated and tested in laboratory-scale mixer-settlers on a genuine phosphoric acid industrial solution. The continuous counter-current test was very successful and showed the possibility to recover more than 95% of uranium decontaminated from the main impurities. A Fe/U ratio of 0.03% was measured in the uranium product, which confirms the high potential of this new solvent for the further production of nuclear-grade uranium from phosphate ores.