Three-component hybrid catalyst for direct synthesis of isoparaffin via modified Fischer–Tropsch synthesis

Direct isoparaffin synthesis method from syngas was developed by using a hybrid catalyst composed of Fischer–Tropsch synthesis catalyst, ZSM-5 zeolite, and Pd/SiO 2, where normal paraffin from Fischer–Tropsch synthesis was hydrocracked in situ on ZSM-5 and Pd/SiO 2 stabilized zeolite activity effect...

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Bibliographic Details
Published inCatalysis communications Vol. 4; no. 3; pp. 108 - 111
Main Authors Tsubaki, Noritatsu, Yoneyama, Yoshiharu, Michiki, Keisuke, Fujimoto, Kaoru
Format Journal Article
LanguageEnglish
Published AMSTERDAM Elsevier B.V 01.03.2003
Elsevier
Subjects
Chemistry
Chemistry, Physical
Fischer–Tropsch synthesis
Hydrocracking
Isoparaffin
Palladium catalyst
Physical Sciences
Science & Technology
Zeolite catalyst
Isoparaffin
Zeolite catalyst
Palladium catalyst
Hydrocracking
Fischer–Tropsch synthesis
zeolite catalyst
palladium catalyst
Fischer-Tropsch synthesis
PHASE
isoparaffin
hydrocracking
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Summary:Direct isoparaffin synthesis method from syngas was developed by using a hybrid catalyst composed of Fischer–Tropsch synthesis catalyst, ZSM-5 zeolite, and Pd/SiO 2, where normal paraffin from Fischer–Tropsch synthesis was hydrocracked in situ on ZSM-5 and Pd/SiO 2 stabilized zeolite activity effectively even at pressurized steam atmosphere mainly via spillover effect.
ISSN:1566-7367
1873-3905
DOI:10.1016/S1566-7367(03)00003-7