Kinetic macroscopic description of the microscopic structure of dissolving interfaces: Influence of the electrochemical kinetics

• Published in: Electrochimica acta Vol. 53; no. 14; pp. 4805 - 4817
• Main Authors: Córdoba-Torres, P., Nogueira, Ricardo P.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 30.05.2008; Elsevier
• Subjects: Applied sciences; Chemical Sciences; Chemistry; Computer simulation; Corrosion; Corrosion mechanisms; Dissolution mechanism; Electrochemistry; Exact sciences and technology; General and physical chemistry; Interface structure; Kinetic modeling; Material chemistry; Metals. Metallurgy; Miscellaneous; Study of interfaces; Surface morphology; Interface structure; Dissolution mechanism; Kinetic modeling; Computer simulation; Surface morphology; Corrosion mechanism; Theoretical study; Electrode electrolyte interface; Modeling; Surface structure; Kinetic model; Anodic dissolution; Kinetics; computer simulation; surface morphology; interface structure; dissolution mechanism; kinetic modeling
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2008.01.075

This paper is devoted to the study of the influence of the electrochemical kinetics on the microscopic structure of a metal–electrolyte interface dissolving through anodic dissolution. The effect of intermediate adsorption reactions, single or multiple dissolution paths, and passivation processes, are investigated in terms of surface roughness and adsorbed species organization along the interface. Computer simulations results are compared to theoretical predictions developed from a macroscopic kinetic description based on probability functions emulating the classical mass balance equations. A linear approximation to the relationship between the spatial and temporal scales of the dissolution front allows an analytical investigation of its structure. The consistency of simulation results with the predictions of a rather simple model is promising. Consequences of interface structure are also addressed, in particular, the feedback action on the electrochemical kinetics when non-linear reactions are involved. In that case, quantitative departures of reaction rates from the mean field approximation can also be modeled by considering the local correlations between adsorbates, thus raising the important role of chemical ordering on the interface evolution. Conclusions obtained from this theoretical investigation are in the line of recent observations.