Advanced materials for global carbon dioxide recycling

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Vol. 304; pp. 88 - 96
• Main Authors: Hashimoto, K., Habazaki, H., Yamasaki, M., Meguro, S., Sasaki, T., Katagiri, H., Matsui, T., Fujimura, K., Izumiya, K., Kumagai, N., Akiyama, E.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 31.05.2001
• Subjects: Amorphous Ni–Zr alloy catalysts; CO 2 methanation; Global CO 2 recycling; Nanocrystalline Mn oxide anodes; Nanocrystalline Ni alloy cathodes; Seawater electrolysis; Suppression of CO 2 emissions; Nanocrystalline Ni alloy cathodes; Nanocrystalline Mn oxide anodes; Amorphous Ni–Zr alloy catalysts; CO 2 methanation; Global CO 2 recycling; Suppression of CO 2 emissions; Seawater electrolysis
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/S0921-5093(00)01457-X

CO 2 emission increase inducing global warming occurs mostly with the growth of the economic activity. Global CO 2 recycling can prevent global warming and supply abundant renewable energy. Global CO 2 recycling consists of three district: The electricity is generated by solar cells on deserts. At coasts close to the deserts, the electricity is used for hydrogen production by seawater electrolysis and hydrogen is used for methane production by the reaction with CO 2. Methane (CH 4) is liquefied and transported to energy consuming districts where after CH 4 is used as a fuel CO 2 is recovered, liquefied and transported to the coasts close to the deserts. Key materials necessary for the global CO 2 recycling are the anode and cathode for seawater electrolysis and the catalyst for CO 2 conversion. All of them have been tailored by us. Amorphous and nanocrystalline nickel alloys are active cathodes for hydrogen production in seawater electrolysis. Anodically deposited nanocrystalline Mn–Mo and Mn–W oxides are the unique substance which can evolve oxygen with 100% efficiency without evolving chlorine in seawater electrolysis. Amorphous Ni–Zr alloys are excellent precursors of catalysts for conversion of CO 2 into CH 4 by the reaction with hydrogen at 1 atm. A prototype CO 2 recycling plant to supply clean energy preventing global warming has been built on the roof of our Institute (IMR) in 1996 using these key materials and has been operating successfully.