Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions

• Published in: Energy & environmental science Vol. 11; no. 1; pp. 45 - 56
• Main Authors: Guo, Chunxian, Ran, Jingrun, Vasileff, Anthony, Qiao, Shi-Zhang
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 01.01.2018
• Subjects: Ammonia; Catalysis; Catalysts; Chemical reduction; Design; Electrocatalysts; Energy consumption; Free energy; Haber Bosch process; High temperature; Physicochemical properties; Renewable energy
• ISSN: 1754-5692; 1754-5706
• DOI: 10.1039/c7ee02220d

As one of the most important chemicals and carbon-free energy carriers, ammonia (NH 3 ) has a worldwide annual production of ∼150 million tons, and is mainly produced by the traditional high-temperature and high-pressure Haber-Bosch process which consumes massive amounts of energy. Very recently, electrocatalytic and photo(electro)catalytic reduction of N 2 to NH 3 , which can be performed at ambient conditions using renewable energy, have received tremendous attention. The overall performance of these electrocatalytic and photo(electro)catalytic systems is largely dictated by their core components, catalysts. This perspective for the first time highlights the rational design of electrocatalysts and photo(electro)catalysts for N 2 reduction to NH 3 under ambient conditions. Fundamental theory of catalytic reaction pathways for the N 2 reduction reaction and the corresponding material design principles are introduced first. Then, recently developed electrocatalysts and photo(electro)catalysts are summarized, with a special emphasis on the relationship between their physicochemical properties and NH 3 production performance. Finally, the opportunities in this emerging research field, in particular, the strategy of combining experimental and theoretical techniques to design efficient and stable catalysts for NH 3 production, are outlined. This perspective highlights the rational design of efficient electrocatalysts and photo(electro)catalysts for N 2 reduction to ammonia (NH 3 ) under ambient conditions.