Synthesis of layer-structured ferroelectric Bi3NbTiO9 plate-like seed crystals

Pure bismuth layered-structure ferroelectric Bi3NbTiO9 plate-like seed crystals were synthesised by the molten-salt method in NaCl-KCl flux using Bi3NbTiO9 precursor from precipitation. Single phase Bi3NbTiO9 powder was obtained in the NaCl-KCl flux at 700 C for only 0.5 h, which is 200 C lower than...

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Published inMaterials letters Vol. 59; no. 14-15; pp. 1876 - 1879
Main Authors Xiang, Ping-Hua, Kinemuchi, Yoshiaki, Watari, Koji
Format Journal Article
LanguageEnglish
Published 01.06.2005
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Summary:Pure bismuth layered-structure ferroelectric Bi3NbTiO9 plate-like seed crystals were synthesised by the molten-salt method in NaCl-KCl flux using Bi3NbTiO9 precursor from precipitation. Single phase Bi3NbTiO9 powder was obtained in the NaCl-KCl flux at 700 C for only 0.5 h, which is 200 C lower than the formation temperature of pure Bi3NbTiO9 Aurivillius phase without chloride salts. The Bi3NbTiO9 platelet synthesised at 900 C is well-dispersed with a diameter of 5-10 micron and aspect ratio of 25-50. 16 refs.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
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ISSN:0167-577X
DOI:10.1016/j.matlet.2005.02.003