Solubility product of a Nb–N bearing austenitic stainless-steel biomaterial

• Published in: Journal of materials research and technology Vol. 15; pp. 5864 - 5879
• Main Authors: Silva, Kayron Lima, Rodrigues, Samuel Filgueiras, Macedo, Glaucia Maria Evangelista, Sousa Lopes, Bruno Leonardy, Aranas, Clodualdo, Siciliano, Fulvio, Reis, Gedeon Silva, Silva, Eden Santos
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2021; Elsevier
• Subjects: Austenitic stainless steel; Grain refinement; Orthopedic implants; Precipitation; Solubility product; Orthopedic implants; Austenitic stainless steel; Precipitation; Solubility product; Grain refinement
• ISSN: 2238-7854
• DOI: 10.1016/j.jmrt.2021.11.033

This research investigates the Z-Phase solubility product of austenitic stainless steel (ASS) ASTM F-1586 used as orthopedic implants under the solubilization procedure. Precipitate extraction by an electrolytic separation technique and analytical thermodynamic calculations as a function of the solubilization temperature and chemical composition were employed. In the first procedure of preferential electrolytic phase dissolution, samples were submitted to a solubilization treatment, followed by quenching. The specimens were subjected to a surface treatment then dissolved in solution. Following the dissolution, the electrolyte was vacuum filtered on a 0.20 μm polyvinylidene difluoride (PVDF) membrane and vacuum dried for 24 h. The microstructures were characterized via scanning electron microscopy (SEM/EDS) and transmission electron microscopy (TEM/EDX) techniques. The results revealed by the Z-phase (Cr2Nb2N2) precipitation potential (Ks) that the precipitates acted as a softening inhibitor agent and retarded the grain growth at lower solubilization temperature conditions (Ts < 1100 °C). The considerable amount of fine precipitates were mainly formed due to the nucleation and coalescence of Cr/NbN in the matrix. On the other hand, larger precipitates nucleated and coalesced above 1200 °C, and had their volume fraction reduced at this condition.