s‐Block Multiple Bonds: Isolation of a Beryllium Imido Complex

• Published in: Angewandte Chemie International Edition Vol. 60; no. 17; pp. 9407 - 9411
• Main Authors: Wang, Guocang, Walley, Jacob E., Dickie, Diane A., Molino, Andrew, Wilson, David J. D., Gilliard, Robert J.
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 19.04.2021
• Edition: International ed. in English
• Subjects: Beryllium; Beryllium compounds; carbene; Chemical bonds; Chemical synthesis; Computer applications; Density functional theory; Magnetic resonance spectroscopy; metal-ligand multiple bonds; Molecular structure; Nitrogen; NMR; NMR spectroscopy; Nuclear magnetic resonance; Oxidation; s-block; beryllium; metal-ligand multiple bonds; carbene; s-block
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.202016027

A common feature of d‐ and p‐block elements is that they participate in multiple bonding. In contrast, the synthesis of compounds containing homo‐ or hetero‐nuclear multiple bonds involving s‐block elements is extremely rare. Herein, we report the synthesis, molecular structure, and computational analysis of a beryllium imido (Be=N) complex (2), which was prepared via oxidation of a molecular Be0 precursor (1) with trimethylsilyl azide Me3SiN3 (TMS‐N3). Notably, compound 2 features the shortest known Be=N bond (1.464 Å) to date. This represents the first compound with an s‐block metal‐nitrogen multiple bond. All compounds were characterized experimentally with multi‐nuclear NMR spectroscopy (1H, 13C, 9Be) and single‐crystal X‐ray diffraction studies. The bonding situation was analyzed with density functional theory (DFT) calculations, which supports the existence of π‐bonding between beryllium and nitrogen. The first s‐block metal‐nitrogen double bond is synthesized! The shortest beryllium‐nitrogen bond has been prepared via oxidation of Be0.