Alumoxane Hydride and Aluminum Chalcogenide Hydride Compounds with Pyrazolato Ligands

Two five‐coordinate Al atoms are present in the planar Al2O2 core in 1, which was prepared from an aluminum dihydride and dioxane; unusually short Al−O bonds are also observed. The aluminum dihydride starting material reacts with Group 16 elements (S, Se, and Te) to provide further chalcogen‐bridged...

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Published inAngewandte Chemie International Edition Vol. 39; no. 23; pp. 4276 - 4279
Main Authors Zheng, Wenjun, Mösch-Zanetti, Nadia C., Roesky, Herbert W., Noltemeyer, Mathias, Hewitt, Manuel, Schmidt, Hans-Georg, Schneider, Thomas R.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 01.12.2000
WILEY‐VCH Verlag GmbH
Wiley
Subjects
aggregation
aluminum
chalcogens
Chemistry
Chemistry, Multidisciplinary
coordination chemistry
N ligands
Physical Sciences
Science & Technology
TE
STRUCTURAL-CHARACTERIZATION
ARYL
GA
AL-O
AB-INITIO
N ligands
aggregation
aluminum
chalcogens
coordination chemistry
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Summary:Two five‐coordinate Al atoms are present in the planar Al2O2 core in 1, which was prepared from an aluminum dihydride and dioxane; unusually short Al−O bonds are also observed. The aluminum dihydride starting material reacts with Group 16 elements (S, Se, and Te) to provide further chalcogen‐bridged aluminum hydrides.
Bibliography:istex:FE7445C660EA3393E1C17471BC13AA732DCEEA55
ArticleID:ANIE4276
ark:/67375/WNG-8ZFN3GMX-M
This work was supported by the Deutsche Forschungsgemeinschaft. N.C.M.‐Z. thanks the Schweizerischer Nationalfonds for a fellowship and W.Z. thanks Dr. U. Ritter for the GC analysis.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20001201)39:23<4276::AID-ANIE4276>3.0.CO;2-8