Enhanced Tunability Achieving at Low Permittivity and Electric Field in (Ba0.91Ca0.09)(SnxZr0.2−xTi0.8)O3-2 mol% CuO-1 mol% Li2CO3 Ceramics

• Published in: Materials Vol. 16; no. 15; p. 5226
• Main Authors: Wang, Bo, Zhao, Le, Jia, Xiuhuai, Yang, Pan, Yu, Shihui
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 25.07.2023; MDPI
• Subjects: Antennas; Ceramics; Communication; Crystal structure; Dielectric properties; Electric fields; ferroelectric varactors; Ferroelectricity; Grain size; Impedance matching; Lithium carbonate; oxygen octahedron; Permittivity; Phase transitions; Scanning electron microscopy; Varactor diodes; Japan
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma16155226

Ferroelectric varactors should have high tunability at low permittivity and a working electric field to obtain better impedance matching and stable tunability. In this work, (Ba0.91Ca0.09)(SnxZr0.2−xTi0.8)O3-2 mol% CuO-1 mol% Li2CO3 (abbreviated as BCSZT100x, x = 0.05, 0.10, 0.15 and 0.20, respectively) are prepared to achieve high tunability at low permittivity and a working electric field. The tunable mechanisms are investigated based on crystal structure, micro-morphology and the permittivity-temperature spectrum. The results show that the shrink of oxygen octahedron and weaker interaction force between Sn4+ and O2− make BCSZT5 ceramic have a higher tunability value of 26.55% at low permittivity (1913) and a working electric field (7.3 kV/cm). The tunability value of BCSZT5 ceramic increases by 58%, while its permittivity decreases by 25%, compared with x = 0. Those advantages make BCSZT5 ceramic have substantial application prospects in varactors.