Fe-g-C3N4/graphitized mesoporous carbon composite as an effective Fenton-like catalyst in a wide pH range

• Published in: Applied catalysis. B, Environmental Vol. 201; pp. 232 - 240
• Main Authors: Ma, Jianqing, Yang, Qunfeng, Wen, Yuezhong, Liu, Weiping
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.02.2017
• Subjects: Catalyst; Fenton-like reaction; Graphitic carbon nitride; Organic pollutant; Fenton-like reaction; Organic pollutant; Catalyst; Graphitic carbon nitride
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2016.08.048

[Display omitted] •Modified g-C3N4 is used as a Fenton-like catalyst in a wide pH range.•The prepared Fe-g-C3N4/GMC catalyst is adaptable to different organic pollutants.•Fe-N centers as active sites were proved.•The enhancement of electron transfer is responsive for these excellent performances. Heterogeneous Fe-N complexes are a kind of promising catalysts for the Fenton-like reaction. The present study selected a stable and inexpensive g-C3N4 as the chelating agent and combined with the graphitized mesoporous carbon (GMC). The fabricated Fe-g-C3N4/GMC composite was characterized by several techniques including FTIR, XRD, XPS, TEM and STXM. Results showed clear sheets of g-C3N4 and graphite with Fe evenly distributed mostly in the Fe-N coordination form. The catalyst expressed high activity in the Fenton-like reaction in a wide pH range of 4–10. 99.2% removal of Acid Red 73 was obtained in 40min, and the degradation data well fitted with the pseudo-first-order kinetics model. By correlating the constant of reaction rates calculated from the model and the Fe speciation contents of the samples prepared at different conditions, we deduced that Fe-N species are the most important active sites for the Fenton-like reaction. More importantly, hydroxyl radicals played a great role in the whole reaction yet their generation was independent of visible light. Cyclic voltammetry results confirmed that the GMC can accelerate the Fe(III)/Fe(II) redox cycle by enhancing electron transfer, and thus enable this Fenton-like catalyst to perform well in a wide pH range.