(Bipyridine-κ 2 N , N ′)chlorido[ N -(2-hydroxyethyl)- N -isopropyldithiocarbamato-κ 2 S , S ′]zinc(II)

The Zn II atom in the title compound, [Zn(C 6 H 12 NOS 2 )Cl(C 10 H 8 N 2 )], is coordinated by a chelating N -2-hy­droxy­ethyl- N -isopropyl­dithio­carbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN 2 S 2 donor set defines a distorted square-pyramidal coordination geometry....

Full description

Saved in:
Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. 7; pp. m958 - m959
Main Authors Mohamad, Fatin Allia, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.07.2012
Subjects
Metal-Organic Papers
Online AccessGet full text

Cover

More Information
Summary:The Zn II atom in the title compound, [Zn(C 6 H 12 NOS 2 )Cl(C 10 H 8 N 2 )], is coordinated by a chelating N -2-hy­droxy­ethyl- N -isopropyl­dithio­carbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN 2 S 2 donor set defines a distorted square-pyramidal coordination geometry. Helical supra­molecular chains sustained by O—H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C—H⋯O, C—H⋯S and C—H⋯Cl inter­actions.
Bibliography:Additional correspondence author, e-mail: aibi@ukm.my.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812027626