Periconiasin G, a new cytochalasan with unprecedented 7/6/5 tricyclic ring system from the endophytic fungus Periconia sp
[Display omitted] Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the first cytochalasan with a 7/6/5 tricyclic ring system, and compound 2 possesses a rare sulfoxide group. Their structures including absolute co...
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Published in | Tetrahedron letters Vol. 57; no. 7; pp. 796 - 799 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
17.02.2016
Elsevier |
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Abstract | [Display omitted]
Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the first cytochalasan with a 7/6/5 tricyclic ring system, and compound 2 possesses a rare sulfoxide group. Their structures including absolute configurations were elucidated by extensive spectroscopic analyses and ECD calculations. A possible biogenetic pathway for these two compounds was proposed. Compound 1 showed weak anti-HIV activity with IC50 value of 67.0μM. |
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AbstractList | [Display omitted]
Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the first cytochalasan with a 7/6/5 tricyclic ring system, and compound 2 possesses a rare sulfoxide group. Their structures including absolute configurations were elucidated by extensive spectroscopic analyses and ECD calculations. A possible biogenetic pathway for these two compounds was proposed. Compound 1 showed weak anti-HIV activity with IC50 value of 67.0μM. Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the first cytochalasan with a 71615 tricyclic ring system, and compound 2 possesses a rare sulfoxide group. Their structures including absolute configurations were elucidated by extensive spectroscopic analyses and ECD calculations. A possible biogenetic pathway for these two compounds was proposed. Compound 1 showed weak anti-HIV activity with IC50 value of 67.0 mu M. (C) 2016 Elsevier Ltd. All rights reserved. Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the first cytochalasan with a 7/6/5 tricyclic ring system, and compound 2 possesses a rare sulfoxide group. Their structures including absolute configurations were elucidated by extensive spectroscopic analyses and ECD calculations. A possible biogenetic pathway for these two compounds was proposed. Compound 1 showed weak anti-HIV activity with IC sub(50) value of 67.0 mu M. |
Author | Yu, Li-Yan Li, Li Dai, Jungui Fang, Xiaomei Tao, Xiaoyu Zhang, Dewu Chen, Ridao Liu, Jimei Zhang, Min |
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Keywords | Cytochalasan Periconiasin Periconia Endophytic fungus SYNTHASE CELLS GENE-CLUSTER CHAETOMIUM-GLOBOSUM CHAETOGLOBOSIN DERIVATIVES |
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Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the... Two new cytochalasans, periconiasin G (1) and periconiasin H (2) were isolated from endophytic fungus Periconia sp. F-31. Compound 1 is the first cytochalasan... |
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SubjectTerms | Chemistry Chemistry, Organic Cytochalasan Endophytic fungus Human immunodeficiency virus Periconia Periconiasin Physical Sciences Science & Technology |
Title | Periconiasin G, a new cytochalasan with unprecedented 7/6/5 tricyclic ring system from the endophytic fungus Periconia sp |
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