Controllable design of solid-state perovskite solar cells by SCAPS device simulation

• Published in: Solid-state electronics Vol. 126; pp. 75 - 80
• Main Authors: Tan, Kai, Lin, Peng, Wang, Gang, Liu, Yan, Xu, Zongchang, Lin, Yixin
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.12.2016
• Subjects: Controllable design; Device simulation; SCAPS; Solid-state perovskite solar cells; SCAPS; Device simulation; Solid-state perovskite solar cells; Controllable design
• ISSN: 0038-1101; 1879-2405
• DOI: 10.1016/j.sse.2016.09.012

•SCAPS device simulator is utilized to analyze and discuss operating mechanism of solid-state perovskite solar cell.•There is an optimal thickness range for efficient device.•The defect density of TiO2/perovskite has stronger impact than that of HTM/perovskite on power conversion efficiency.•The selection of suitable doping additive and doping level for HTM layer needs to weigh hole mobility and acceptor density.•The devices with PTAA and CuI, as HTM candidates, both achieve outstanding power conversion efficiency (17.4%). The highest power conversion efficiency (PCE) of solid-state perovskite solar cells (ssPSCs) has achieved 20.1% recently. There isreason tobelieve that ssPSCs is a strong competitor with silicon and CIGS solar cells in photovoltaic field. The deep understanding of operation mechanism of ssPSCs is essential and required to furtherly improve device performance. The configuration and excition type are similar to inorganic semiconductor solar cells. Therefore, Solar Cell Capacitance Simulator (SCAPS), a device simulator widely using in inorganic solar cells, was employed to controllably design ssPSCs. The validity of device simulation was verified by comparing with real devices from reported literatures. The influence of absorber thickness on device property was discussed, which indicate that it exists an optimal thickness range. Two hypothetical interface layers, TiO2/perovskite layer and perovskite/HTM layer, were introduced into the construction model to consider the effects of interfaces defect density on device performance. It revealed TiO2/perovskite has stronger impact than perovskite/HTM, because higher excess carrier density existing at TiO2/perovskite will cause more recombination rate. In addition, hole transport materials (HTM) parameters, hole mobility and acceptor density, were chosen to study the impact of HTM characteristics on PCE. The analysis illuminate that the design of HTM layer should balance hole mobility and acceptor density. Meanwhile, different HTM candidates were selected and replaced typical HTM layer. The discussion about the function of candidates on solar cells performance demonstrated that a thiophene group hole-transporting polymer (PTAA) and a copper-based conductor (CuI) both have relatively high PCE, which is due to their wide bandgap, high conductivity, and better chemical interaction with perovskite absorber.