Polymer Complexes of Rhodium Acetamidate Dimers Bridged by Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane

• Published in: Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) Vol. 379; no. 1; pp. 327 - 332
• Main Authors: Handa, Makoto, Muraki, Yasuhiro, Kawabata, Seiichiro, Sugimori, Tamotsu, Hiromitsu, Ichiro, Mikuriya, Masahiro, Kasuga, Kuninobu
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Philadelphia, PA Taylor & Francis Group 01.01.2002; Gordon and Breach
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Conductivity phenomena in semiconductors and insulators; Electronic transport in condensed matter; Exact sciences and technology; Inorganic compounds; Low-field transport and mobility; piezoresistance; Magnetic properties and materials; Magnetically ordered materials: other intrinsic properties; Metal complexes; Physics; Saturation moments and magnetic susceptibilities; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Inorganic compounds; Transition element complexes; Mixed-valence compounds; Electrical conductivity; Electrical properties; Nitrogen heterocycle; Organic ligand; Magnetic moments; XRD; Experimental study; Magnetic susceptibility; Mu complex; Rhodium II Rhodium III Complexes; Complexes Mixed; Six membered ring; Polynuclear complex; Bicyclic compound; Carboxamide; Rhodium II Complexes; Magnetic properties; Crystal structure
• ISSN: 1542-1406; 1058-725X; 1563-5287
• DOI: 10.1080/713738649

Polymer complexes of rhodium (II,II and II,III) acetamidate dimers bridged by pyrazine (pyz), 4,4'-bipyridine (4,4'-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco) have been prepared and characterized. Doping of the Rh(II,II) polymers with NOBF 4 increased the electrical conductivities when the bridging ligands were pyz and 4,4'-bpy. The magnetic interaction through the bridging ligands was found to be weak for the Rh(II,III) polymers. polymer complexes rhodium acetamidate pyrazine 4,4'-bipyridine 1,4-diazabicyclo[2.2.2]octane magnetism conductivity