Carbon capture and conversion using metal-organic frameworks and MOF-based materials
Rapidly increasing atmospheric CO 2 concentrations threaten human society, the natural environment, and the synergy between the two. In order to ameliorate the CO 2 problem, carbon capture and conversion techniques have been proposed. Metal-organic framework (MOF)-based materials, a relatively new c...
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| Published in | Chemical Society reviews Vol. 48; no. 1; pp. 2783 - 2828 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
20.05.2019
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Rapidly increasing atmospheric CO
2
concentrations threaten human society, the natural environment, and the synergy between the two. In order to ameliorate the CO
2
problem, carbon capture and conversion techniques have been proposed. Metal-organic framework (MOF)-based materials, a relatively new class of porous materials with unique structural features, high surface areas, chemical tunability and stability, have been extensively studied with respect to their applicability to such techniques. Recently, it has become apparent that the CO
2
capture capabilities of MOF-based materials significantly boost their potential toward CO
2
conversion. Furthermore, MOF-based materials' well-defined structures greatly facilitate the understanding of structure-property relationships and their roles in CO
2
capture and conversion. In this review, we provide a comprehensive account of significant progress in the design and synthesis of MOF-based materials, including MOFs, MOF composites and MOF derivatives, and their application to carbon capture and conversion. Special emphases on the relationships between CO
2
capture capacities of MOF-based materials and their catalytic CO
2
conversion performances are discussed.
This review summarizes recent advances and highlights the structure-property relationship on metal-organic framework-based materials for carbon dioxide capture and conversion. |
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| Bibliography: | 2 capture and mechanistic studies of CO Hai-Long Jiang received his PhD (2008) from Fujian Institute of Research on the Structure of Matter, CAS. He subsequently worked at the National Institute of Advanced Industrial Science and Technology (AIST, Japan), first as an AIST Fellow and later as a JSPS Fellow during 2008-2011. After a postdoctoral stint at Texas A&M University (USA), he was appointed as a full professor at USTC in 2013. He is a Fellow of the Royal Society of Chemistry (FRSC) and was recognized as a highly cited researcher (2017 & 2018) in chemistry by Clarivate Analytics. His main research interest is the development of crystalline porous and nanostructured materials, crossing coordination chemistry and nanoscience, for catalysis. capture and conversion. Robinson W. Flaig received his BS degree (2014) in chemistry from UW-Platteville. He is currently a PhD student under the guidance of Prof. Omar Yaghi at UC Berkeley. His research focuses on the development of new MOFs and COFs for CO Meili Ding received her BS degree (2014) in chemistry from Anhui Normal University. She is currently a PhD student under the guidance of Prof. Hai-Long Jiang at University of Science and Technology of China (USTC). Her research focuses on metal-organic framework-based materials for CO chemisorption reactions. Omar M. Yaghi received his PhD from the University of Illinois-Urbana, and studied as an NSF Postdoctoral Fellow at Harvard University. He is currently the James and Neeltje Tretter Chair Professor of Chemistry at UC Berkeley and a Senior Faculty Scientist at Lawrence Berkeley National Laboratory. He is also the Founding Director of the Berkeley Global Science Institute as well as the Co-Director of the Kavli Energy NanoScience Institute and the California Research Alliance by BASF. He is interested in the science of building chemical structures from organic and inorganic molecular building blocks (Reticular Chemistry) to make extended porous structures, such as MOFs, COFs, and ZIFs. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 ObjectType-Review-3 content type line 23 |
| ISSN: | 0306-0012 1460-4744 1460-4744 |
| DOI: | 10.1039/c8cs00829a |