Effect of gas composition on the kinetics of iron oxide reduction in a hydrogen production process

• Published in: International journal of hydrogen energy Vol. 30; no. 15; pp. 1543 - 1554
• Main Authors: Piotrowski, Krzysztof, Mondal, Kanchan, Lorethova, Hana, Stonawski, Lubor, Szymański, Tomasz, Wiltowski, Tomasz
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.12.2005; Elsevier
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Energy; Exact sciences and technology; Fuels; Hematite; Hydrogen; Iron oxides phase transformations; Iron oxides reduction; Isothermal solid-state reaction kinetics; Johnson–Mehl–Avrami–Erofe’ev equation; Magnetite; Thermogravimetric experiments; Topochemical reactions; Wüsite; Hematite; Thermogravimetric experiments; Topochemical reactions; Iron oxides phase transformations; Magnetite; Johnson–Mehl–Avrami–Erofe’ev equation; Wüsite; Iron oxides reduction; Isothermal solid-state reaction kinetics; Johnson-Mehl-Avrami-Erofe'ev equation; Iron oxide; Carbon dioxide; Thermogravimetry; Composition effect; Synthesis gas; Chemical reduction; Phase transformation; Wiisite; Kinetics; Activation energy; Comparative study; Hydrogen production
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2004.10.013

Fe 2 O 3 is a suitable oxygen transfer agent for converting CO present in syngas to CO 2 for its eventual separation from H 2 . However, H 2 also reacts with iron oxide to form H 2 O . In order to evaluate the reactions for hydrogen enrichment, investigations into Fe 2 O 3 to FeO reduction kinetics in the presence of syngas constituents were conducted. The reaction kinetic parameters were estimated based on the thermogravimetric data. Hancock and Sharp method of comparing the kinetics of isothermal solid-state reactions, based on Johnson–Mehl–Avrami–Erofe’ev equation describing nucleation and growth processes, was applied. The experimental results indicate that the reduction is initially a surface-controlled process, but once a thin layer of lower iron oxides (magnetite, wüsite) is formed on the surface, the mechanism shifts to diffusion control. It was concluded that this initial stage of the reaction process could be interpreted as a both phase-boundary-controlled reaction and the two-dimensional nucleation and growth (transformation of the crystallographic lattices of higher oxide to lattices of lower oxide) at the gas/iron oxide interface. Comparison of the reaction courses for both the reducing agents ( H 2 , CO) independently and for their mixture was performed. It was found, that the reaction rate increases with, both, temperature and the hydrogen content in inlet gas. The activation energy values were estimated and compared.