Evaluating water quality and ecotoxicology assessment techniques using data from a lead and zinc effected upland limestone catchment

• Published in: Water research (Oxford) Vol. 128; pp. 49 - 60
• Main Authors: Valencia-Avellan, Magaly, Slack, Rebecca, Stockdale, Anthony, Mortimer, Robert John George
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.01.2018
• Subjects: Bioavailability; Calcium Carbonate - analysis; Calcium Carbonate - chemistry; Ecotoxicology; England; Environmental Monitoring - methods; Lead - analysis; Lead - chemistry; Limestone catchment; Metal assessment; Mining; Risk Assessment; River water; Water Pollutants, Chemical - analysis; Water Quality; Water quality standards; Zinc - analysis; Zinc - chemistry; Limestone catchment; Water quality standards; Bioavailability; Metal assessment; Ecotoxicology; River water
• ISSN: 0043-1354; 1879-2448
• DOI: 10.1016/j.watres.2017.10.031

Point and diffuse sources associated with historical metal ore mining are major causes of metal pollution. The understanding of metal behaviour and fate has been improved by the integration of water chemistry, metal availability and toxicity. Efforts have been devoted to the development of efficient methods of assessing and managing the risk posed by metals to aquatic life and meeting national water quality standards. This study focuses on the evaluation of current water quality and ecotoxicology techniques for the metal assessment of an upland limestone catchment located within a historical metal (lead ore) mining area in northern England. Within this catchment, metal toxicity occurs at circumneutral pH (6.2–7.5). Environmental Quality Standards (EQSs) based on a simple single concentration approach like hardness based EQS (EQS-H) are more overprotective, and from sixteen sites monitored in this study more than twelve sites (>75%) failed the EQSs for Zn and Pb. By increasing the complexity of assessment tools (e.g. bioavailability-based (EQS-B) and WHAM-FTOX), less conservative limits were provided, decreasing the number of sites with predicted ecological risk to seven (44%). Thus, this research supports the use of bioavailability-based approaches and their applicability for future metal risk assessments. [Display omitted] •In carboniferous catchments, Zn and Pb toxic effects occur at circumneutral pH.•Metal assessment with EQS-H tools is more conservative than EQS-B and WHAM-FTOX.•Bioavailability-based tools support remediation to reach good ecological status.