A physics based reduced order aging model for lithium-ion cells with phase change

• Published in: Journal of power sources Vol. 270; pp. 281 - 291
• Main Authors: Gambhire, Priya, Hariharan, Krishnan S., Khandelwal, Ashish, Kolake, Subramanya Mayya, Yeo, Taejung, Doo, Seokgwang
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.12.2014; Elsevier
• Subjects: Applied sciences; Direct energy conversion and energy accumulation; Electric cells; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrodes; Electrolytic cells; Exact sciences and technology; Lithium batteries; Lithium ion cells; Lithium iron phosphate; Mathematical models; Phase change; Phase change electrodes; Power management; Reduced order; Reduced order model; Lithium iron phosphate; Lithium ion cells; Reduced order model; Phase change electrodes; Lithium ion batteries; Phase change; Ageing; Iron Phosphates; Electrochemical cell; Secondary cell; Electrodes; Phase transformation; Lithium Phosphates; Models; Alkaline cell
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2014.07.127

The electrochemical model has the potential to provide a robust and accurate battery management system, but is not the preferred choice as it involves solving non-linear, coupled partial differential equations. In the present work, a model order reduction of the complete electrochemical model for a lithium ion cell with phase change electrodes is carried out. The phase change phenomenon is described using a simple, concentration-dependent diffusivity derived from mixture rules. This reduced order model (ROM) is validated with experimental data from literature. The applicability of the model to capture the atypical behavior of the phase change electrode system is demonstrated. Using the cell response from ROM, charge–discharge asymmetry and path dependence in a lithium iron phosphate (LFP) cell are explored in detail. In addition, side reaction kinetics and solid electrolyte interphase formation are included in the ROM framework to enhance its capability to predict cell aging. The model is used to investigate capacity losses occurring in a phase change electrode cell. Insights from these results are used to suggest cell operating guidelines for maximizing utilization. •Reduced order model for cells with phase change electrodes.•Two phase coexistence described using a concentration dependent diffusivity.•Easy implementation of degradation to study the cycle life.•Model captures experimentally observed signatures of phase transition and aging.