High-temperature tensile and creep properties of a ferritic stainless steel for interconnect in solid oxide fuel cell

• Published in: Journal of power sources Vol. 196; no. 4; pp. 2005 - 2012
• Main Authors: Chiu, Yung-Tang, Lin, Chih-Kuang, Wu, Jiunn-Chi
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.02.2011; Elsevier
• Subjects: Applied sciences; Correlation; Creep (materials); Creep properties; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Exponents; Ferritic stainless steel; Ferritic stainless steels; Fuel cells; High temperature; Holes; Planar solid oxide fuel cell; Rupture; Solid oxide fuel cells; Steels; Stresses; Tensile properties; Ferritic stainless steel; Creep properties; High temperature; Planar solid oxide fuel cell; Tensile properties; Creep; Interconnection; Tensile property; Solid oxide fuel cell; Planar technology
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2010.09.083

The purpose of this study is to investigate the high-temperature mechanical properties of a ferritic stainless steel (Crofer 22 APU) for use as an interconnect material in planar solid oxide fuel cells (pSOFCs). Tensile properties of the Crofer 22 APU steel are evaluated at temperatures of 25–800 °C. Creep properties are evaluated by constant-load tests at 650–800 °C. Several creep lifetime models are applied to correlate the creep rupture time with applied stress or minimum creep rate. Experimental results show the variation of yield strength with temperature can be described by a sigmoidal curve for different deformation mechanisms. The creep stress exponent, n, has a value of 5 or 6, indicating a power-law creep mechanism involving dislocation motion. The apparent activation energy for such a power-law creep mechanism is estimated as 393 kJ mol −1 through some thermally activated relations. Creep rupture time of the Crofer 22 APU steel can be described by a Monkman–Grant relation with a time exponent, m = 1.11. The relation between creep rupture time and normalized stress is well fitted by a universal simple power law for all of the given testing temperatures. Larson–Miller relationship is also applied and shows good results in correlating the creep rupture time with applied stress and temperature for the Crofer 22 APU steel. Fractographic and microstructural observations indicate most of the creep cavities are nucleated along grain boundaries and a greater amount of cavities are formed under high stresses.