Stereoselective synthesis towards the C8–C18 subunit of pamamycin-607 induced by a chiral sulfoxide group

A close precursor of the C8–C18 subunit of pamamycin-607 was prepared by asymmetric synthesis from ethyl butyryl acetate via a chiral β,δ-diketosulfoxide.

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Bibliographic Details
Published inTetrahedron letters Vol. 41; no. 4; pp. 551 - 554
Main Authors Solladié, Guy, Salom-Roig, Xavier J, Hanquet, Gilles
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 01.01.2000
Elsevier
Subjects
Chemical Sciences
Chemistry
Chemistry, Organic
Organic chemistry
Physical Sciences
Science & Technology
(+)-NONACTIC ACID
SHORT ASYMMETRIC-SYNTHESIS
ANTIBIOTICS
REDUCTION
STREPTOMYCES-ALBONIGER
SUBSTANCE
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Summary:A close precursor of the C8–C18 subunit of pamamycin-607 was prepared by asymmetric synthesis from ethyl butyryl acetate via a chiral β,δ-diketosulfoxide.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(99)02117-6