A multi-stimuli responsive ruthenium complex for catalytic water oxidation

A ruthenium complex showing multi-stimuli-responsive isomerization was synthesized. The catalytic activity of this complex toward water oxidation showed responses to visible-light irradiation and heat due to photoisomerization and thermal back-isomerization, respectively. DFT calculations suggested...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 56; no. 84; pp. 12825 - 12828
Main Authors Hirahara, Masanari, Goto, Hiroki, Yagi, Masayuki, Umemura, Yasushi
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 28.10.2020
Subjects
Catalytic activity
Chemical synthesis
Crystallography
Electrochemistry
Isomerization
Light irradiation
NMR
Nuclear magnetic resonance
Oxidation
Ruthenium compounds
Stimuli
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Summary:A ruthenium complex showing multi-stimuli-responsive isomerization was synthesized. The catalytic activity of this complex toward water oxidation showed responses to visible-light irradiation and heat due to photoisomerization and thermal back-isomerization, respectively. DFT calculations suggested that a pendant moiety in the complex was key to controlling the catalytic activity. A ruthenium complex showing multi-stimuli-responsive isomerization was synthesized.
Bibliography:1
For ESI and crystallographic data in CIF or other electronic format see DOI
2014033
H NMR and UV-Vis spectroscopic data, electrochemistry, and water oxidation experiments. CCDC
2014032
and
Electronic supplementary information (ESI) available: Experimental details
10.1039/d0cc04940a
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc04940a