Impact of solid-state photochemical [2+2] cycloaddition on coordination polymers for diverse applications
Photochemical [2+2] cycloaddition reactions have been developed as a promising route to generate photoswitchable structures and a wide variety of frameworks. There are numerous examples of discrete molecules that undergo cycloaddition reactions. However, photocycloaddition in coordination polymers (...
Saved in:
| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 49; no. 28; pp. 9556 - 9563 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
28.07.2020
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Summary: | Photochemical [2+2] cycloaddition reactions have been developed as a promising route to generate photoswitchable structures and a wide variety of frameworks. There are numerous examples of discrete molecules that undergo cycloaddition reactions. However, photocycloaddition in coordination polymers (CPs) with potential applications is relatively less explored. Hence, the synthesis of such novel photoreactive CPs for diverse applications is a challenging task. This Frontier article highlights recent advances in the solid-state [2+2] cycloaddition of CPs and its impact on their applications.
This Frontier article highlights the advancement of [2+2] photocycloaddition reactions within coordination polymers to fine tune their diverse physical and chemical properties. |
|---|---|
| Bibliography: | Basudeb Dutta completed his Bachelor's (2013) and Master's (2015) degree from Jadavpur University, Kolkata, India. He has recently submitted his thesis work for obtaining his PhD degree under the supervision of Dr Mohammad Hedayetullah Mir at Aliah University, Kolkata, India. His research interest includes the design and synthesis of photoreactive coordination polymers for conductivity, Schottky diodes, catalysis, magnetism, sensing, popping of crystals He received the 'IUCr Young Scientist Award' at the 16th Conference of the Asian Crystallographic Association (AsCA 2019), National University of Singapore, Singapore, December 2019. etc Mohammad Hedayetullah Mir obtained his PhD degree from the National University of Singapore, Singapore, under the supervision of Prof. J. J. Vittal. He did his postdoctoral training under Prof. Susumu Kitagawa (Kyoto University, Japan) on the ERATO KITAGAWA Integrated Pores Project, Japan Science and Technology (JST) Agency. Since 2010, he has been actively involved in teaching and scientific research at the Aliah University, Kolkata, India, where he is currently an assistant professor. He received the 'Outstanding Scientist Award' and 'Young Scientist Award' in chemical sciences from Venus International Foundation for the years 2018 and 2017, respectively. He has also been acknowledged with The Best Research Publication Award (2010), the AsCA Travel Award (2009) and The Best Graduate Researcher Award (2008). His current research interests are in the areas of photoreactive metal-organic framework (MOF)/coordination polymers (CPs) and their application in gas storage, electrical conductivity, catalysis, magnetism, sensing, DNA binding Samim Khan completed his Integrated Master's degree at Aliah University, Kolkata, India, in 2015. He obtained his PhD from Jadavpur University, Kolkata, India, under the guidance of Dr Shouvik Chattopadhyay in 2019. He is currently working as CSIR Research Associate with Dr Mohammad Hedayetullah Mir at Aliah University, Kolkata. His current research interests include the design and synthesis of flexible metal-organic frameworks (MOFs) for on-demand guest molecular trapping or storage systems, electrical conductivity and sensing. He was bestowed with the 'Best Poster Award' on Chemical Crystallography sponsored by Crystal Growth & Design at the 16th Conference of the Asian Crystallographic Association (AsCA 2019), National University of Singapore, Singapore, December 2019. . ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/d0dt01534b |