Standard mixtures of ambient volatile organic compounds in synthetic and whole air with stable reference values
Research into the role of volatile organic compounds (VOCs) in the chemistry of the lower atmosphere has led to requirements for stable and accurate standard gas mixtures to underpin long‐term monitoring of global background and polluted urban concentrations. We describe a novel method for the prepa...
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Published in | Journal of Geophysical Research: Atmospheres Vol. 115; no. D14 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
Blackwell Publishing Ltd
27.07.2010
American Geophysical Union |
Subjects | |
Online Access | Get full text |
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Summary: | Research into the role of volatile organic compounds (VOCs) in the chemistry of the lower atmosphere has led to requirements for stable and accurate standard gas mixtures to underpin long‐term monitoring of global background and polluted urban concentrations. We describe a novel method for the preparation of standard mixtures containing thirty compounds in matrices of nitrogen and whole air. The estimated uncertainty in the amount fractions of the compounds in these mixtures is typically 2% (relative) and typical stability is better than 0.2% per annum. We also report the results of a comparison exercise between eight laboratories using these mixtures, which indicate that typical uncertainties achievable by laboratories making measurements of these compounds are better than demonstrated previously. |
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Bibliography: | Tab-delimited Table 1.Tab-delimited Table 2.Tab-delimited Table 3.Tab-delimited Table 4.Tab-delimited Table 5.Tab-delimited Table 6. ArticleID:2009JD012933 ark:/67375/WNG-ZM5CN366-2 istex:6C95DED0D141EBDEB1405B03AD62884F1FDA988B ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0148-0227 2169-897X 2156-2202 2169-8996 |
DOI: | 10.1029/2009JD012933 |