Water-Vapor-Induced Reversible Switching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity

Back and forth: Reversible structural change and changes in the physical properties of a quasi‐1D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge‐polarization and charge‐density‐wave (ACP+CDW) state to a narrow...

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Published inAngewandte Chemie (International ed.) Vol. 49; no. 3; pp. 552 - 555
Main Authors Iguchi, Hiroaki, Takaishi, Shinya, Miyasaka, Hitoshi, Yamashita, Masahiro, Matsuzaki, Hiroyuki, Okamoto, Hiroshi, Tanaka, Hisaaki, Kuroda, Shin-ichi
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 12.01.2010
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
chain structures
electric conductors
phase transitions
platinum
reversible dehydration
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Summary:Back and forth: Reversible structural change and changes in the physical properties of a quasi‐1D dinuclear Pt complex occurred with dehydration and rehydration. Upon dehydration, the electronic state changed from an alternating charge‐polarization and charge‐density‐wave (ACP+CDW) state to a narrow‐gapped CDW state with an increase in the electrical conductivity and molar spin susceptibility at room temperature.
Bibliography:http://dx.doi.org/10.1002/anie.200905608
Ministry of Education, Culture, Sports, Science, and Technology
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ArticleID:ANIE200905608
istex:1A008FB74B638EB5A528659D81362113C1D7064A
We acknowledge Prof. Maekawa and Ando at Tohoku University for acquiring the 31P MAS NMR spectra. This work was partly supported by a Grant-in-Aid for Creative Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology.
P MAS NMR spectra. This work was partly supported by a Grant‐in‐Aid for Creative Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology.
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We acknowledge Prof. Maekawa and Ando at Tohoku University for acquiring the
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905608