First preparation and structural determination of 1,1-disubstituted dibenzo[bc,fg][1,4]silathiapentalene derivatives by x-ray crystallographic analysis and MO calculations

• Published in: Heteroatom chemistry Vol. 7; no. 2; pp. 143 - 147
• Main Authors: Kimura, Takeshi, Izumi, Yukiko, Furukawa, Naomichi, Minoshima, Yoshihiro
• Format: Journal Article
• Language: English
• Published: Florida VCH Publishers, Inc 1996
• ISSN: 1042-7163; 1098-1071
• DOI: 10.1002/(SICI)1098-1071(199603)7:2<143::AID-HC7>3.0.CO;2-E

1,1‐Dimethyldibenzo[bc,fg][1,4]silathiapentalene (1a) was prepared by treatment of 1,9‐bis(methyl‐sulfinyl)dibenzothiophene with EtMgBr or of dibenzothiophene with n‐butyllithium, and then with dimethyl dichlorosilane. The structure of 4,4‐dimethyl‐dibenzo[bc,fg][1,4]silathiapentalene 1‐oxide (2), obtained by oxidation of compound 1a with mCPBA, was determined by X‐ray crystallographic analysis. The structure of compound 2 determined experimentally was compared to the structure obtained by semiempirical molecular orbital calculations (AM1). The MO calculations of compound 1a and its phenyl analog 1b were also performed by AM1 to evaluate their structures. © 1996 John Wiley & Sons, Inc.