Neutral Lewis Base Adducts of Silicon Tetraazide

Highly energetic and still stable: The first base adducts of silicon tetraazide, Si(N3)4(L2) (L2=bipyridine, 1,10‐phenanthroline), were prepared and fully characterized (picture: the ball and stick model of the adduct with L2=2,2'‐bipyridine in front of its FTIR spectrum; dark gray C, white H,...

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Published inAngewandte Chemie (International ed.) Vol. 49; no. 43; pp. 8013 - 8016
Main Authors Portius, Peter, Filippou, Alexander C, Schnakenburg, Gregor, Davis, Martin, Wehrstedt, Klaus-Dieter
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 18.10.2010
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
azides
hypercoordination
N ligands
nitrogen-rich compounds
silicon
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Summary:Highly energetic and still stable: The first base adducts of silicon tetraazide, Si(N3)4(L2) (L2=bipyridine, 1,10‐phenanthroline), were prepared and fully characterized (picture: the ball and stick model of the adduct with L2=2,2'‐bipyridine in front of its FTIR spectrum; dark gray C, white H, light gray Si, blue N). The highly energetic compounds combine a remarkable thermal stability, with a high reactive nitrogen content (up to 48 %) and convenient accessibility.
Bibliography:http://dx.doi.org/10.1002/anie.201001826
ArticleID:ANIE201001826
Deutsche Forschungsgemeinschaft
EPSRC
Humboldt-Universität zu Berlin
istex:81915FCC13BB6DFA5F4413B9D8A6CDDA1A77DE73
ark:/67375/WNG-TDQX8FSF-R
We thank the Deutsche Forschungsgemeinschaft SFB 813 (A.C.F.), the EPSRC (fellowship to P.P.), and the Humboldt-Universität zu Berlin for financial support.
We thank the Deutsche Forschungsgemeinschaft SFB 813 (A.C.F.), the EPSRC (fellowship to P.P.), and the Humboldt‐Universität zu Berlin for financial support.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201001826