Mercury[rightward arrow]Antimony Interaction

Fatal attraction: As a result of a unique iodide push–stibonium pull effect, the dinuclear complex (see picture) displays an unprecedented Hg→Sb interaction. The existence of this interaction was examined experimentally and theoretically.

Saved in:
Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 49; no. 36; pp. 6357 - 6360
Main Authors Lin, Tzu-Pin, Wade, Casey R, Pérez, Lisa M, Gabbaï, François P
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 23.08.2010
WILEY-VCH Verlag
WILEY‐VCH Verlag
Wiley
Subjects
antimony
Chemistry
Chemistry, Multidisciplinary
hypervalence
Lewis acids
mercury
Physical Sciences
Science & Technology
transition metals
DATIVE BONDS
antimony
BLOCK METALS
APPROXIMATION
mercury
BEHAVIOR
transition metals
AB-INITIO
COMPLEXES
Lewis acids
OXIDATION-STATE IV
hypervalence
REGULAR 2-COMPONENT HAMILTONIANS
LIGANDS
TRANSITION-METAL
Online AccessGet full text

Cover

More Information
Summary:Fatal attraction: As a result of a unique iodide push–stibonium pull effect, the dinuclear complex (see picture) displays an unprecedented Hg→Sb interaction. The existence of this interaction was examined experimentally and theoretically.
Bibliography:http://dx.doi.org/10.1002/anie.201002995
ArticleID:ANIE201002995
Welch Foundation - No. A-1423
ark:/67375/WNG-6V8XBVSG-2
National Science Foundation - No. CHE-0646916; No. CHE-0952912
Support by the National Science Foundation (CHE-0646916 and CHE-0952912), the Welch Foundation (A-1423), Texas A&M University (Davidson Professorship), and the Laboratory for Molecular Simulation at Texas A&M University (software and computation resources) is gratefully acknowledged.
istex:CFFFFF053D00B67BE2134315DE5DF1860FB7EFA4
Support by the National Science Foundation (CHE‐0646916 and CHE‐0952912), the Welch Foundation (A‐1423), Texas A&M University (Davidson Professorship), and the Laboratory for Molecular Simulation at Texas A&M University (software and computation resources) is gratefully acknowledged.
National Science Foundation
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201002995