Influence of reactor material and activated carbon on the thermocatalytic decomposition of methane for hydrogen production

• Published in: Applied catalysis. A, General Vol. 388; no. 1; pp. 232 - 239
• Main Authors: Abbas, Hazzim F., Daud, W.M.A. Wan
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 20.11.2010; Elsevier
• Subjects: Activated carbon; Adsorbents; Catalysis; Catalytic methane decomposition; Chemistry; Colloidal state and disperse state; Decomposition; Decomposition reactions; Exact sciences and technology; Flow rate; General and physical chemistry; Hydrogen production; Methane; Particle size; Pilot plant; Porous materials; Reactor materials; Reactors; Surface physical chemistry; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Pilot plant; Catalytic methane decomposition; Activated carbon; Hydrogen production; Methane; Particle size; Catalytic reaction; Flow rate; Deactivation; Micropore; Hydrogen; Conversion rate; Fixed bed reactor; Decomposition; Porous material; Velocity; Heterogeneous catalysis; Dilution; Microporosity; Stainless steel; Inverse; Rate constant; Reactor
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2010.08.057

[Display omitted] ▶ Stainless-steel reactor seriously affects decomposition at a temperature >850 °C. ▶ Changing the AC particle size (135–1095 μm) did not have a significant effect. ▶ The reaction results obtained by increasing the VHSV using two different methods indicated that the methods did not affect the measured AC initial activity. ▶ Various measurements revealed that decomposition occurs mainly within AC micropores. A series of experiments was conducted to study the catalytic effects of the stainless-steel reactor material and activated carbon (AC) on the decomposition of methane for production of hydrogen. Additionally, the effects of the methane flow rate, amount of AC, decomposition temperature, and particle size on methane conversion, initial decomposition rate and deactivation time were determined in a fixed bed reactor. The reactor wall seriously affected the methane decomposition when the temperature was higher than 850 °C. The activity of the AC increased with the increase in methane decomposition temperature (775–850 °C), and changing the particle size (135–1095 μm) did not have a significant effect. The initial rate of methane decomposition showed an inverse and non-linear relationship with increasing weight of AC due to the dilution of methane by the produced hydrogen. However, the method of changing the volume hourly space velocity, i.e., by changing either the AC weight at a constant methane flow rate or the methane flow rate at a constant AC weight, did not cause differences in the measured AC initial activity. Various measurements on the AC at the beginning and end of the experiment revealed that methane decomposition occurs mainly within AC micropores.