Thermally induced oxygen related defects in eco-friendly ZnFe2O4 nanoparticles for enhanced wastewater treatment efficiencies

• Published in: Chemosphere (Oxford) Vol. 288; p. 132525
• Main Authors: Al-Najar, Basma, Younis, Adnan, Hazeem, Layla, Sehar, Shama, Rashdan, Suad, Shaikh, M. Nasiruzzaman, Albuflasa, Hanan, Hankins, Nicholas P.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.02.2022
• Subjects: Crystal size; Cytotoxicity; Dye mineralisation; Oxygen vacancies; Photocatalysis; Picochlorum sp; Crystal size; Cytotoxicity; Oxygen vacancies; Picochlorum sp; Dye mineralisation; Photocatalysis
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2021.132525

Herein, a simple but highly effective strategy of thermal annealing to modulate oxygen vacancies related defects in ZnFe2O4 (ZFO) nanoparticles for obtaining enhanced wastewater treatment efficiencies is reported. The as-prepared nanoparticles were thermally annealed at three different temperatures (500 °C, 600 °C and 700 °C) and their phase purity was confirmed by X-ray diffraction (XRD). All samples were found to exhibit pure phases of ZFO with different crystallite sizes ranging from 10 nm to 25 nm. The transmission electron microscope (TEM) images showed well dispersed nanoparticles and a strong correlation of grain size growth with annealing temperature was established. The optical absorption and emission characteristics were estimated through UV–visible and Photoluminescence (PL) spectroscopy. Raman spectroscopy and X-ray Photoelectron Spectroscopy (XPS) confirmed the variation of oxygen vacancies in the synthesized samples’ lattice. The photocatalytic activities of all samples were investigated and the highest efficiencies were recorded for the ZFO samples annealed at 500 °C. Under high salinity condition, the organic dye degradation efficiency of the same sample remained the highest among all. The excellent dye degradation abilities in ZFO samples can be attributed to the abundance of oxygen vacancies in the crystal lattice that slow down the recombination rate during the photocatalysis process. Moreover, cytotoxicity tests revealed that all prepared ZFO samples showed insignificant cell structure effects on Picochlorum sp microalgae, as verified by Fourier-transform infrared (FTIR) spectroscopy. On the other hand, no significant changes were detected on the viable cell concentration and Chlorophyll a content. This work presents a systematic way to finely tune the crystal sizes and to modulate oxygen related defects in ZFO through a highly effective annealing approach to signify their potential in industrial wastewater and seawater treatment processes. [Display omitted] •Nanocrystalline ZnFe2O4 (ZFO) nanoparticles were fabricated using a facile precipitation method.•Thermal post annealing was conducted to tune the crystalline structure and oxygen related defects in ZFO nanoparticles.•The post annealed ZFO nanoparticles showed excellent photocatalytic response in aqueous solution as well as in seawater.•The modulation of oxygen vacancies are critical to finely tune degradation efficiencies in ZFO nanoparticles.