Hydrodynamic interaction and coalescence of two droplets under large step shear strains

• Published in: Polymer (Guilford) Vol. 49; no. 8; pp. 2014 - 2017
• Main Authors: Okamoto, Kenzo, Iwatsuki, Shigenori, Ishikawa, Masaru, Takahashi, Masaoki
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 15.04.2008; Elsevier
• Subjects: Applied sciences; Coalescence; Droplet; Exact sciences and technology; Hydrodynamic interaction; Organic polymers; Physicochemistry of polymers; Properties and characterization; Rheology and viscoelasticity; Coalescence; Droplet; Hydrodynamic interaction; Dimethylsiloxane polymer; Isobutene polymer; Polymer blends; Molten state; Shear flow; Kinetics; Experimental study; Heterogeneous mixture
• ISSN: 0032-3861; 1873-2291
• DOI: 10.1016/j.polymer.2008.03.003

We observed change in distance between two droplets in each step after application of large multi-step shear strains. Experiments were performed using a sliding plate apparatus. Large step shear strains were applied to two polyisobutylene droplets in poly(dimethyl siloxane) matrix in the same plane between the plates. The distance between the two droplets decreases with increasing the total shear strain, which is given by the product of the step strain magnitude and the number of application of the step strains. The two droplets coalesce when the distance becomes less than the diameter of the droplets. The slope for plots of the distance versus the total strain is independent of the step strain magnitude. This indicates that the effect per unit strain on the distance is the same, irrespective of the strain magnitude. It is suggested that a stronger hydrodynamic interaction between the droplets is the main cause for the droplet approach.