Photocatalytic performance of magnesium alloy microarc oxides

• Published in: Journal of alloys and compounds Vol. 562; pp. 84 - 89
• Main Authors: Tang, Mingqi, Li, Gang, Li, Weiping, Liu, Huicong, Zhu, Liqun
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 15.06.2013; Elsevier
• Subjects: Catalysis; Catalysts: preparations and properties; Chemistry; Coatings; Corrosion resistance; Corrosion tests; Electrochemical impedance spectroscopy; Electrolytes; Exact sciences and technology; General and physical chemistry; Magnesium alloy; Magnesium base alloys; Microarc oxidation; Phosphates; Photocatalysis; Photocatalytic; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Titanium dioxide; Microarc oxidation; Corrosion resistance; Photocatalytic; Magnesium alloy; Potentiodynamic method; Phase composition; Surface morphology; Photocatalysis; Corrosion test; Microstructure; Coatings; Plasma electrolytic oxidation
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2013.02.051

► MAO coatings were prepared in a stabilized phosphate electrolyte with K2TiF6. ► Anatase TiO2 and Mg2TiO4 were defined in the MAO coating. ► The addition of K2TiF6 increased the corrosion resistance of the MAO coatings. ► The MAO coatings formed in electrolyte with K2TiF6 exhibited photocatalytic performance. Microarc oxidation (MAO) coatings were prepared on AZ91D magnesium alloy in a phosphate electrolyte with and without K2TiF6, respectively. The morphology, composition and phase structure of the MAO coatings were investigated. Corrosion resistances and photocatalytic properties of the MAO coatings were evaluated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) in 3.5wt.% NaCl solution and photocatalytic decomposition of methylthionine blue (MB) solution in incandescent light. Gray coatings formed in the phosphate electrolyte were mainly composed of MgO and amorphous phase. Compared with the phosphate electrolyte, black coatings with fewer and smaller micropores were formed in the electrolyte with K2TiF6. Moreover, Titanium in the form of Mg2TiO4 and TiO2 was detected in the black coatings. The results of corrosion tests show that the MAO coatings formed in the phosphate electrolyte with and without K2TiF6 both improved significantly the corrosion resistance of the magnesium alloy. Photocatalytic measurements indicated that the MAO coatings formed in the electrolyte with K2TiF6 exhibited photocatalytic behaviors.