Design and synthesis of dinuclear hemisalen complex on hexaarylbenzene scaffold

The dinuclear vanadium(V)-dihemisalen complexes on the hexaarylbenzene scaffold were designed and synthesized, where the characteristic behaviors were found in the complexation of the dihemisalen ligand with VO(OiPr)3. The dinuclear vanadium(V) dihemisalen complexes on the hexaarylbenzene scaffold w...

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Bibliographic Details
Published inTetrahedron letters Vol. 53; no. 42; pp. 5589 - 5592
Main Authors Miyasaka, Akihiro, Amaya, Toru, Hirao, Toshikazu
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 17.10.2012
Elsevier
Subjects
Chemistry
Chemistry, Organic
Complexation
Dinuclear complex
Hemisalen ligand
Ligands
Physical Sciences
Scaffolds
Science & Technology
Synthesis (chemistry)
Tetrahedrons
Vanadium
Dinuclear complex
Vanadium
Hemisalen ligand
OXIDATION
DUAL ACTIVATION
BIOMIMICS
2-NAPHTHOLS
CHEMISTRY
VANADIUM CATALYSTS
H2O2
OXOVANADIUM(IV) COMPLEXES
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Summary:The dinuclear vanadium(V)-dihemisalen complexes on the hexaarylbenzene scaffold were designed and synthesized, where the characteristic behaviors were found in the complexation of the dihemisalen ligand with VO(OiPr)3. The dinuclear vanadium(V) dihemisalen complexes on the hexaarylbenzene scaffold were designed and synthesized, where the characteristic behaviors were found in the complexation of the dihemisalen ligand with VO(OiPr)3.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2012.07.127