Dehydrogenative Dimerization of Di-tert-butyltin Dihydride Photochemically and Thermally Catalyzed by Iron and Molybdenum Complexes
Tin–tin bonds are formed in the title reaction, which provides tBu2HSnSnHtBu2 in high yield. The reaction is either photochemically catalyzed by the iron complex [(η5‐C5H5)Fe(CO)2Me] or its molybdenum analogue [(η5‐C5H5)Mo(CO)3Me] or thermally catalyzed by [(η5‐C5H5)Fe(CO)(PPh3)Me] or its analogue...
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Published in | Angewandte Chemie (International ed.) Vol. 48; no. 34; pp. 6309 - 6312 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley-VCH Verlag
10.08.2009
WILEY-VCH Verlag WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | Tin–tin bonds are formed in the title reaction, which provides tBu2HSnSnHtBu2 in high yield. The reaction is either photochemically catalyzed by the iron complex [(η5‐C5H5)Fe(CO)2Me] or its molybdenum analogue [(η5‐C5H5)Mo(CO)3Me] or thermally catalyzed by [(η5‐C5H5)Fe(CO)(PPh3)Me] or its analogue [(η5‐C5H5)Mo(CO)2(PPh3)Me]. |
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Bibliography: | http://dx.doi.org/10.1002/anie.200902327 Welch Foundation - No. AH-546 istex:C268658770CE082318045CC1DBDA8ED9CABF4A9C NIH ArticleID:ANIE200902327 This work was supported by Welch Foundation, Houston, TX (Grant AH-546) and the NIH-MARC U-STAR program. ark:/67375/WNG-9VPPKBMT-V This work was supported by Welch Foundation, Houston, TX (Grant AH‐546) and the NIH‐MARC U‐STAR program. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200902327 |