Ordered mesoporous carbon preparation by the in situ radical polymerization of acrylamide and its application for resorcinol removal
ABSTRACT In this study, acrylamide (AM) was, for the first time, successfully used to synthesize ordered mesoporous carbon (OMC) through in situ polymerization inside SBA‐15 (Santa Barbara Amorphous type material) as a hard template. A straightforward and environmentally friendly method was proposed...
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Published in | Journal of applied polymer science Vol. 133; no. 19; pp. np - n/a |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Hoboken
Blackwell Publishing Ltd
15.05.2016
Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
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Summary: | ABSTRACT
In this study, acrylamide (AM) was, for the first time, successfully used to synthesize ordered mesoporous carbon (OMC) through in situ polymerization inside SBA‐15 (Santa Barbara Amorphous type material) as a hard template. A straightforward and environmentally friendly method was proposed and verified with an emphasis on the precursor modification for the preparation of OMC. The influences of the structure and the amount of SBA‐15 on the OMC structure and adsorption capacity were evaluated. To improve the adsorption capacity and yield, the following three approaches were tried: (1) the use of concentrated sulfuric acid (H2SO4) to fix carbon and nitrogen, (2) the use of a crosslinking agent, and (3) the addition of melamine as a possible nitrogen source. The adsorption capacities for resorcinol were evaluated, and they showed an improvement of 37% in comparison with that of the commercially available granular activated carbon (27 mg/g). Well‐OMC materials were obtained with higher yields with H2SO4 and crosslinking agent compared with those obtained for the pure AM precursor. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43426. |
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Bibliography: | ArticleID:APP43426 Louisiana Board of Regents istex:14CC5B8CD9A501109EC1679C7121F6F7D1341F11 National Aeronautics and Space Administration - No. NNX10AI40H ark:/67375/WNG-M9XVNJTQ-8 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0021-8995 1097-4628 |
DOI: | 10.1002/app.43426 |