Impact of hydrological alterations on river-groundwater exchange and water quality in a semi-arid area: Nueces River, Texas

• Published in: The Science of the total environment Vol. 572; pp. 595 - 607
• Main Authors: Murgulet, Dorina, Murgulet, Valeriu, Spalt, Nicholas, Douglas, Audrey, Hay, Richard G.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.12.2016
• Subjects: Calcium Carbonate - chemistry; Carbon Isotopes - analysis; Chlorides - analysis; Climate; Dam; Electric Conductivity; Freshwater; Geochemistry; Groundwater - analysis; Groundwater - chemistry; Hydrologic alteration; Hydrology - methods; Nueces River; Oxygen Isotopes - analysis; Power Plants; Radon - analysis; Resistivity; Rivers; Sulfates - analysis; Texas; Tomography - methods; Water Quality; ASW, USA, Texas; USA, Texas, Nueces R; Geochemistry; Dam; Hydrologic alteration; Nueces River; Texas; Resistivity
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2016.07.198

There is a lack of understanding and methods for assessing the effects of anthropogenic disruptions, (i.e. river fragmentation due to dam construction) on the extent and degree of groundwater-surface water interaction and geochemical processes affecting the quality of water in semi-arid, coastal catchments. This study applied a novel combination of electrical resistivity tomography (ERT) and elemental and isotope geochemistry in a coastal river disturbed by extended drought and periodic flooding due to the operation of multiple dams. Geochemical analyses show that the saltwater barrier causes an increase in salinity in surface water in the downstream river as a result of limited freshwater inflows, strong evaporation effects on shallow groundwater and mostly stagnant river water, and is not due to saltwater intrusion by tidal flooding. Discharge from bank storage is dominant (~84%) in the downstream fragment and its contribution could increase salinity levels within the hyporheic zone and surface water. When surface water levels go up due to upstream freshwater releases the river temporarily displaces high salinity water trapped in the hyporheic zone to the underlying aquifer. Geochemical modeling shows a higher contribution of distant and deeper groundwater (~40%) in the upstream river and lower discharge from bank storage (~13%) through the hyporheic zone. Recharge from bank storage is a source of high salt to both upstream and downstream portions of the river but its contribution is higher below the dam. Continuous ERT imaging of the river bed complements geochemistry findings and indicate that while lithologically similar, downstream of the dam, the shallow aquifer is affected by salinization while fresher water saturates the aquifer in the upstream fragment. The relative contribution of flows (i.e. surface water releases or groundwater discharge) as related to the river fragmentation control changes of streamwater chemistry and likely impact the interpretation of seasonal trends. [Display omitted] •Hydrologic alterations in coastal rivers and semi-arid climates affect water chemistry.•Stable isotopes of δ18O and δD constrain well the magnitude of groundwater contribution.•Variable degrees of groundwater discharge occur downstream and upstream of the dam.•Electrical resistivity methods show sources and quality of groundwater discharge.•Evaporation effects significantly alter surface water and groundwater quality.