Membrane processes for removal of pharmaceutically active compounds (PhACs) from water and wastewaters

• Published in: The Science of the total environment Vol. 547; pp. 60 - 77
• Main Authors: Taheran, Mehrdad, Brar, Satinder K., Verma, M., Surampalli, R.Y., Zhang, T.C., Valero, J.R.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 15.03.2016
• Subjects: Filtration - instrumentation; Membrane bioreactor; Membrane separation; Nanofiltration; Pharmaceutical Preparations - analysis; Pharmaceutically active compounds (PhACs); Reverse osmosis; Waste Disposal, Fluid - methods; Waste Water - chemistry; Water Pollutants, Chemical - analysis; Water Purification - methods; UV; Membrane bioreactor; GAC; FO; MW; Pharmaceutically active compounds (PhACs); NOM; PhACs; Membrane separation; UF; Nanofiltration; MWCO; PAC; WWTP; NF; COD; Reverse osmosis; MLSS; MBR; Da; RO; WHO
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2015.12.139

Pharmaceutically active compounds (PhACs), which find their way easily into the water sources, are emerging as a major concern for drinking water quality and aquatic species. Therefore, their removal from water sources is a priority from environmental point of view. During the past decade, different methods including membrane separation, adsorption systems and chemical transformation have been evaluated for removal of these compounds. This paper reviews different aspects of PhAC removal by using membrane separation processes, as they have been conventionally known to show high potential in the production of superior quality drinking and industrial water. In brief, osmosis membranes can efficiently remove almost all PhACs though its operational cost is relatively high and nanofiltration (NF) membranes are highly influenced by electrostatic and hydrophobic interaction. Moreover, the efficiency of membrane bioreactors (MBRs) is difficult to predict due to the complex interaction of compounds with microorganisms. To improve the performance and robustness of membrane technology, it is suggested to combine membranes with other systems, such as activated carbon and enzymatic degradation. [Display omitted] •RO systems can remove almost all kinds of PhACs with more than 75% removal rate.•NF systems show high rejections for PhACs, but are influenced by several parameters.•MBRs show erratic removals (0-90%) due to effects of compounds on microorganisms.•Combining or integrating membranes with other systems can improve their performances.