Effect of oxalic acid content and medium of thermal treatment on physicochemical and catalytic properties of MoVTeNb oxide catalysts in propane ammoxidation

• Published in: Applied catalysis. A, General Vol. 328; no. 2; pp. 195 - 200
• Main Authors: Popova, G.Ya, Andrushkevich, T.V., Aleshina, G.I., Plyasova, L.M., Khramov, M.I.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 10.09.2007; Elsevier
• Subjects: Acrylonitrile; Ammoxidation; MoVTeNb mixed oxide; Phase structure; Propane; M1; Acrylonitrile; M2; Ammoxidation; MoVTeNb mixed oxide; Phase structure; Propane
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2007.06.010

Catalytic characteristics of MoV 0.3Te 0.23Nb 0.12O x catalysts in propane ammoxidation depend strongly on the quantity of oxalic acid present during slurry preparation and on the redox conditions during thermal treatment of the catalyst. Two stage thermal treatment (320 °C in air, 600 °C in He) and oxalate anion to niobium ratio in the slurry С 2О 4 2−/Nb = 3–5 have been shown to result in the catalysts with the best catalytic properties. Optimal catalysts have been found to contain M1 and M2 crystalline phases in the ratio of 3:1 or more. When the molar ratio С 2О 4 2−/Nb exceeds 3.5, tellurium is lost during calcination in He and other phases beside M1 and M2 are formed. ▪ Catalytic characteristics of MoV 0.3Te 0.23Nb 0.12O x catalysts in propane ammoxidation depend strongly on the quantity of oxalic acid present during slurry preparation and on the redox conditions during thermal treatment of the catalyst. Two stage thermal treatment (320 °C in air, 600 °C in He) and oxalate anion to niobium ratio in the slurry С 2О 4 2−/Nb = 3–5 have been shown to result in the catalysts with the best catalytic properties. Optimal catalysts have been found to contain M1 and M2 crystalline phases in the ratio of 3:1 or more. When the molar ratio С 2О 4 2−/Nb exceeds 3.5, tellurium is lost during calcination in He and other phases beside M1 and M2 are formed.